Simultaneous determination of dissolved organic carbon and total dissolved nitrogen in seawater by high temperature catalytic oxidation: conditions for precise shipboard measurements
نویسندگان
چکیده
Appropriate conditions have been achieve d for the accurate, rapid, and highly precise shipboard simultaneous determination of dissolved organic carbon and total dissolved nitrogen in seawater by high tem perature catalytic oxidation. A nitrogen-specific Antek 705D chemiluminescence detector and a CO 2-specific LiCor Li6252 IRGA have been coupled inseries with a Shimadzu TOC-5000 organic carbon analy ser. Precision of both sim ultaneous measurements is 1.5%, i.e., ±1 μmol C l and ± 0.3 μmol N l , respectively. Quality of analysis is not compromised by vibrations associated with ocean going research vessels.
منابع مشابه
Simultaneous Determination of Dissolved Organic Carbon and Total Dissolved Nitrogen on a Coupled High-Temperature Combustion Total Organic Carbon-Nitrogen Chemiluminescence Detection (HTC TOC-NCD) System
The marine biogeochemistries of carbon and nitrogen have come under increased scrutiny because of their close involvement in climate change and coastal eutrophication. Recent studies have shown that the high-temperature combustion (HTC) technique is suitable for routine analyses of dissolved organic matter due to its good oxidation efficiency, high sensitivity, and precision. In our laboratory,...
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